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Generation of Non-Stabilized Azomethine Ylides 6.

Click Chemistry and Dendrimer Synthesis as Tools for Designing Efficient Optical Power Limiting Platinum(II) Acetylides.

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Trends in Organic Chemistry , 29.

1,3-Dipolar cycloaddition reaction between stabilised azomethine ylides and electrophilic olefins can be performed, diastereoselectively and in good yields, in the presence of substoichiometric amounts of both Ag(I) and inorganic bases.

Recent Research Developments in Organic Chemistry.

F., III, Towards organo-click chemistry: Development of organocatalytic multicomponent reactions through combinations of Aldol, Wittig, Knoevenagel, Michael, Diels-Alder and Huisgen cycloaddition reactions.

L., The Convergence of Synthetic Organic and Polymer Chemistries.

Wittig Reactions in Water Media Employing Stabilized Ylides with Aldehydes.

Following a general overview of 1,3-dipolar cycloadditions, the main body of the review focuses on asymmetric 1,3-dipolar cycloadditions of acrylamides with nitrile oxides, nitrones, diazoalkanes and azomethine ylides, with particular emphasis on the rationale for the observed stereocontrol (215 references).

Combining Proline and 'Click Chemistry': a Class of Versatile Organocatalysts for the Highly Diastereo- and Enantioselective Michael Addition in Water.

R., Two enabling architectures for DNA-templated organic synthesis.

V., Practical synthesis of amides from in situ generated copper(I) acetylides and sulfonyl azides.

V.; Van der Eycken, E., A microwave-assisted click chemistry synthesis of 1,4-disubstituted 1,2,3-triazoles via a copper(I)-catalyzed three-component reaction.

A Click Chemistry Approach to Glycomimetics: Michael Addition of 2,3,4,6-tetra--acetyl-1-thio-β-D-glucopyranose to 4-deoxy-1,2--isopropylidene-L--pent-4-enopyranos-3-ulose - a Convenient Route to Novel 4-deoxy-(1->5)-5--thiodisaccharides.

B., "On water": Unique reactivity of organic compounds in aqueous suspension.
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  • Azomethine Ylides in Organic Synthesis | BenthamScience

    A.; Ham, J., Synthesis of Functionalized Organotrifluoroborates via the 1,3-Dipolar Cycloaddition of Azides.

  • (2003), Azomethine Ylides in Organic Synthesis

    L., Organocatalytic polymerization of ethylene oxide and the controlled synthesis of peo-based hydrogel networks.

  • Azomethine Ylides in Organic Synthesis - ResearchGate

    H.; Kluger, C., Azide/alkyne-"click" reactions: applications in material science and organic synthesis.

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Azomethine Ylides in Organic Synthesis, ChemInform | …

Departamento de Química Orgánica, Universidad de Alicante. E-03080 Alicante, Spain
Tel. +34-96-5903728, Fax +34-96-5903549, E-mail: Abstract: The study of the stereochemistry of substituted prolines, synthesised by 1,3-dipolar cycloaddition reactions between azomethine ylides and alkenes employing substoichiometric amounts of Ag(I) is reported here

They appear in organic chemistry as ..

The synthetic usefulness of this step is demonstrated in generating reactive intermediates such as nitrones, iminium cations, α-amino radicals and azomethine ylides depending on the substrates and reaction medium.

Azomethine Ylides in Organic Synthesis

[3] Silver(I) salts have been employed as Lewis acids in equimolar amounts in 1,3-dipolar cycloaddition reactions with azomethine ylides: Grigg, R.; Hargreves, S. Redpath, J.; Turchi, S.; Yoganathan, G. 1,3-Dipolar cycloaddition reactions of imines of - and -dialdehydes. Applications to the synthesis of novel polyfunctionalised pyrrolizidines and indolizidines. 1999, 441.

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