Generation of Non-Stabilized Azomethine Ylides 6.
Click Chemistry and Dendrimer Synthesis as Tools for Designing Efficient Optical Power Limiting Platinum(II) Acetylides.
Trends in Organic Chemistry , 29.
1,3-Dipolar cycloaddition reaction between stabilised azomethine ylides and electrophilic olefins can be performed, diastereoselectively and in good yields, in the presence of substoichiometric amounts of both Ag(I) and inorganic bases.
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Following a general overview of 1,3-dipolar cycloadditions, the main body of the review focuses on asymmetric 1,3-dipolar cycloadditions of acrylamides with nitrile oxides, nitrones, diazoalkanes and azomethine ylides, with particular emphasis on the rationale for the observed stereocontrol (215 references).
Combining Proline and 'Click Chemistry': a Class of Versatile Organocatalysts for the Highly Diastereo- and Enantioselective Michael Addition in Water.
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A Click Chemistry Approach to Glycomimetics: Michael Addition of 2,3,4,6-tetra--acetyl-1-thio-β-D-glucopyranose to 4-deoxy-1,2--isopropylidene-L--pent-4-enopyranos-3-ulose - a Convenient Route to Novel 4-deoxy-(1->5)-5--thiodisaccharides.
The simple and the complex in organic synthesis.
Azomethine Ylides in Organic Synthesis | BenthamScience
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(2003), Azomethine Ylides in Organic Synthesis
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Azomethine Ylides in Organic Synthesis - ResearchGate
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Azomethine Ylides in Organic Synthesis, ChemInform | …
Departamento de Química Orgánica, Universidad de Alicante. E-03080 Alicante, Spain
Tel. +34-96-5903728, Fax +34-96-5903549, E-mail: Abstract: The study of the stereochemistry of substituted prolines, synthesised by 1,3-dipolar cycloaddition reactions between azomethine ylides and alkenes employing substoichiometric amounts of Ag(I) is reported here
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The synthetic usefulness of this step is demonstrated in generating reactive intermediates such as nitrones, iminium cations, α-amino radicals and azomethine ylides depending on the substrates and reaction medium.
Azomethine Ylides in Organic Synthesis
 Silver(I) salts have been employed as Lewis acids in equimolar amounts in 1,3-dipolar cycloaddition reactions with azomethine ylides: Grigg, R.; Hargreves, S. Redpath, J.; Turchi, S.; Yoganathan, G. 1,3-Dipolar cycloaddition reactions of imines of - and -dialdehydes. Applications to the synthesis of novel polyfunctionalised pyrrolizidines and indolizidines. 1999, 441.
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